Investigation of Orderly Nanostructures and Assembly Modes of Binary Organogels via Glutamic Acid Amino Derivative and Different Fatty Acids
Jiao TF(焦体峰)1,2; Xing, Ruirui1; Shen, Xihai1,3; Zhang, Qingrui1; Zhou JX(周靖欣)1; Gao FM(高发明)1
刊名Integrated Ferroelectrics
2014
卷号151期号:1页码:31-41
关键词Binary organogel supramolecular assembly nanostructure glutamic acid derivative fatty acid
ISSN号1058-4587
通讯作者焦体峰 ; Zhang, Qingrui
英文摘要In this paper the gelation behaviors of binary fatty acids with different length of alkyl chains and glutamic acid amino derivative in various organic solvents were designed and investigated. Their gelation behaviors in 20 solvents were tested as new binary organic gelators. The results showed that the length of alkyl chains has played a crucial role in the gelation behavior of all gelator mixtures in various organic solvents. Longer alkyl chains in molecular skeletons in present gelators are favorable for the gelation of organic solvents. Morphological studies revealed that the gelator molecules self-assemble into different aggregates, such as lamella, rod, belt, and fiber with change of solvents. Spectral studies indicated that there existed different H-bond formation and hydrophobic force, depending on imide segment and alkyl substituent chains in molecular skeletons. In addition, the used solvents had great effect on the assembly modes and stacking units of these binary gelators. The present work may also give new clues for designing new binary organogelators and soft materials.
学科主题材料科学与物理化学
收录类别SCI
资助信息the National Natural Science Foundation of China (Grant No. 21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770;2013T60265);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002)
语种英语
WOS记录号WOS:000337329100006
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/18306]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
3.Hebei Normal Univ Sci & Technol, Coll Phys & Chem, Qinhuangdao 066004, Peoples R China
推荐引用方式
GB/T 7714
Jiao TF,Xing, Ruirui,Shen, Xihai,et al. Investigation of Orderly Nanostructures and Assembly Modes of Binary Organogels via Glutamic Acid Amino Derivative and Different Fatty Acids[J]. Integrated Ferroelectrics,2014,151(1):31-41.
APA Jiao TF,Xing, Ruirui,Shen, Xihai,Zhang, Qingrui,Zhou JX,&Gao FM.(2014).Investigation of Orderly Nanostructures and Assembly Modes of Binary Organogels via Glutamic Acid Amino Derivative and Different Fatty Acids.Integrated Ferroelectrics,151(1),31-41.
MLA Jiao TF,et al."Investigation of Orderly Nanostructures and Assembly Modes of Binary Organogels via Glutamic Acid Amino Derivative and Different Fatty Acids".Integrated Ferroelectrics 151.1(2014):31-41.
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