Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 固体润滑国家重点实验室

	Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain
	Jiao TF(焦体峰)1,2; Xing, Ruirui 1; Zhang, Qingrui 1; Lv, Yaopeng 1; Zhou JX(周靖欣)1; Gao FM(高发明)1
刊名	Journal of Nanomaterials
	2013
ISSN号	1687-4110
通讯作者	焦体峰 ; Zhang, Qingrui
英文摘要	A special naphthyl-containing Schiff base derivative, N,N-bis(2-hydroxy-1-naphthylidene)-1,2-phenylenediamine, was synthesized, and its coordination with various metal ions in situ at the air/water interface has been investigated. Although the ligand contains no alkyl chain, it can be spread on water surface. When metal ions existed in the subphase, an interfacial coordination between the ligand and different metal ions occurred in the spreading film, while different Nanostructures were fabricated in the monolayers. Interestingly to note that among various metal ions, only the in situ coordination-induced Cu(II)-complex film showed supramolecular chirality, although themultilayer films from the ligand or preformed complex are achiral. The chirality of the in situ Cu(II)-coordinated Langmuir film was developed due to the special distorted coordination reaction and the spatial limitation at the air/water interface. A possible organization mechanism at the air/water interface was suggested.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	the National Natural Science Foundation of China (Grant Nos. 20903078; 21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002)
语种	英语
WOS记录号	WOS:000317760200001
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18258]
专题	兰州化学物理研究所_固体润滑国家重点实验室
作者单位	1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Hebei, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China
推荐引用方式 GB/T 7714	Jiao TF,Xing, Ruirui,Zhang, Qingrui,et al. Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain[J]. Journal of Nanomaterials,2013.
APA	Jiao TF,Xing, Ruirui,Zhang, Qingrui,Lv, Yaopeng,Zhou JX,&Gao FM.(2013).Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain.Journal of Nanomaterials.
MLA	Jiao TF,et al."Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain".Journal of Nanomaterials (2013).