Self-Assembly and Soft Material Preparation of Binary Organogels via Aminobenzimidazole/Benzothiazole and Acids with Different Alkyl Substituent Chains

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 固体润滑国家重点实验室

	Self-Assembly and Soft Material Preparation of Binary Organogels via Aminobenzimidazole/Benzothiazole and Acids with Different Alkyl Substituent Chains
	Jiao TF(焦体峰)1,2; Ma, Keren 1; Shen, Xihai 1,3; Zhang, Qingrui 1; Li, Xiujin 1; Zhou JX(周靖欣)1; Gao FM(高发明)1
刊名	Journal of Nanomaterials
	2013
ISSN号	1687-4110
通讯作者	焦体峰
英文摘要	The gelation behaviors of binary organogels composed of aminobenzimidazole/benzothiazole derivatives and benzoic acid with single-/multialkyl substituent chain in various organic solvents were designed and investigated. Their gelation behaviors in 20 solvents were tested as new binary organic gelators. This showed that the number and length of alkyl substituent chains and benzimidazole/benzothiazole segment have played a crucial role in the gelation behavior of all gelator mixtures in various organic solvents. More alkyl chains in molecular skeletons in present gelators are favorable for the gelation of organic solvents. The length of alkyl substituent chains has also played an important role in changing the gelation behaviors and assembly states. Morphological studies revealed that the gelator molecules self-assemble into different aggregates from wrinkle, lamella, belt, to fiber with change of solvents. Spectral studies indicated that there existed different H-bond formation and hydrophobic force, depending on benzimidazole/benzothiazole segment and alkyl substituent chains in molecular skeletons. The prepared nanostructured materials have wide perspectives and many potential applications in nanoscience and material fields due to their scientific values. The present work may also give new clues for designing new binary organogelators and soft materials.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	the National Natural Science Foundation of China (Grant no. 21207112);the Natural Science Foundation of Hebei Province (Grant nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant nos. 2011M500540;2012M510770;2013T60265);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002)
语种	英语
WOS记录号	WOS:000323963900001
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18182]
专题	兰州化学物理研究所_固体润滑国家重点实验室
作者单位	1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.Hebei Normal Univ Sci & Technol, Coll Phys & Chem, Qinhuangdao 066004, Peoples R China
推荐引用方式 GB/T 7714	Jiao TF,Ma, Keren,Shen, Xihai,et al. Self-Assembly and Soft Material Preparation of Binary Organogels via Aminobenzimidazole/Benzothiazole and Acids with Different Alkyl Substituent Chains[J]. Journal of Nanomaterials,2013.
APA	Jiao TF.,Ma, Keren.,Shen, Xihai.,Zhang, Qingrui.,Li, Xiujin.,...&Gao FM.(2013).Self-Assembly and Soft Material Preparation of Binary Organogels via Aminobenzimidazole/Benzothiazole and Acids with Different Alkyl Substituent Chains.Journal of Nanomaterials.
MLA	Jiao TF,et al."Self-Assembly and Soft Material Preparation of Binary Organogels via Aminobenzimidazole/Benzothiazole and Acids with Different Alkyl Substituent Chains".Journal of Nanomaterials (2013).