Spectroscopic Characterizations of Semiquinone Anion Radical Formation and Autosensitized Photooxidation for Elsinochrome A | |
Lao, Wenjian1; Li, Cong2; Tai, Hong3; You, Jinmao4 | |
刊名 | Journal- Chemical Society of Pakistan |
2015 | |
卷号 | 37期号:1页码:99-104 |
关键词 | Elsinochrome A EPR spectra Semiquinone anion radical Autosensitized photooxidation |
ISSN号 | 0253-5106 |
英文摘要 | Elsinochrome A (EA) is a natural perylenequinone known for high photosensitization activity. There are a limited number of studies on its photophysical and photosensitive properties. In this study, formation of semiquinone anion radical and EA autosensitized photooxidation reactions were examined. Rate constant of semiquinone anion radical formation under anaerobic condition, and rate constant of autosensitized photooxidation reaction under aerobic condition were measured for Elsinochrome A (EA) by electron paramagnetic resonance and UV-visible spectra, respectively. The rate constant of formation was estimated at 0.767 min(-1) (R-2 = 0.963) using the zero-order reaction equation. The autosensitized photooxidation reaction occurred only when irradiation and oxygen co-existed in the EA solution. The average reaction rate constant was 3.22 +/- 0.36 (x10(-9), mol.s(-1)), and EA half-life was 4.48 +/- 0.52 (h) in the tetrachloromethane solution. |
收录类别 | SCI |
资助信息 | the Director Foundation of Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences |
语种 | 英语 |
WOS记录号 | WOS:000360064600014 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/18571] |
专题 | 兰州化学物理研究所_非现建制 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China 2.Yunnan Univ, Sch Chem Sci & Technol, Kunming 650091, Peoples R China 3.Johns Hopkins Sch Med, Dept Pathol, Baltimore, MD 21205 USA 4.Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China |
推荐引用方式 GB/T 7714 | Lao, Wenjian,Li, Cong,Tai, Hong,et al. Spectroscopic Characterizations of Semiquinone Anion Radical Formation and Autosensitized Photooxidation for Elsinochrome A[J]. Journal- Chemical Society of Pakistan,2015,37(1):99-104. |
APA | Lao, Wenjian,Li, Cong,Tai, Hong,&You, Jinmao.(2015).Spectroscopic Characterizations of Semiquinone Anion Radical Formation and Autosensitized Photooxidation for Elsinochrome A.Journal- Chemical Society of Pakistan,37(1),99-104. |
MLA | Lao, Wenjian,et al."Spectroscopic Characterizations of Semiquinone Anion Radical Formation and Autosensitized Photooxidation for Elsinochrome A".Journal- Chemical Society of Pakistan 37.1(2015):99-104. |
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