Behavior of borate complex anion on the stabilities and the hydrogen evolutions of ZnxCo3-xO4 decorated graphene

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	Behavior of borate complex anion on the stabilities and the hydrogen evolutions of ZnxCo3-xO4 decorated graphene
	Hao, Xuqiang 1; Jin, Zhiliang 1; Wang, Fang 1; Xu, Jing 1; Min SX(敏世雄)1 ; Yuan, Hong 1; Lu GX(吕功煊)2
刊名	Superlattices and Microstructures
	2015
卷号	82 页码:599-611
关键词	Hydrogen evolution Borate complex anions Graphene Dye-sensitized
ISSN号	0749-6036
通讯作者	Jin, Zhiliang
英文摘要	The electron oscillation of borate complex anions in the borate solution was a very interesting peculiar phenomenon in the study of Solution Chemistry up to now. By means of borate complex anions addition, reacting system inertion and the electrons addition, based on the peculiar contribution of borate complex anions with an electron oscillation characters, the stabilities and the hydrogen evolutions of Zn_xCo₃₋_xO₄ decorated graphene were greatly improved. Here, the photocatalytic activity was dependent on the synergetic effects of borate complex anions and graphene. The structure–activity relationships between the borate complex anions and the Zn_xCo₃₋_xO₄ decorated grapheme were investigated. The borate complex anions can not only contribute to the more efficiently capture electrons from excited Eosin dye but also beneficial to the more efficiently transfer electrons to the decorated catalysts. So the charge separation and the electrons transfer were more efficient in the condition of the borate complex anions addition as supported by fluorescence studies. The synergetic effects between boron and grapheme were due to the double-pathway of synergetic effects for electrons transfer.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation (21263001);the National Natural Science Foundation (21463001);the National Natural Science Foundation (21266001);the State Ethnic Affairs Commission Research Project (12BFZ008);the National Natural Science Foundation (21433007)
语种	英语
WOS记录号	WOS:000357141400058
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18313]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_ERC国家工程研究中心
作者单位	1.Beijang Univ Nationalities, Sch Chem & Chem Engn, Yinchuan 750021, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Hao, Xuqiang,Jin, Zhiliang,Wang, Fang,et al. Behavior of borate complex anion on the stabilities and the hydrogen evolutions of ZnxCo3-xO4 decorated graphene[J]. Superlattices and Microstructures,2015,82:599-611.
APA	Hao, Xuqiang.,Jin, Zhiliang.,Wang, Fang.,Xu, Jing.,Min SX.,...&Lu GX.(2015).Behavior of borate complex anion on the stabilities and the hydrogen evolutions of ZnxCo3-xO4 decorated graphene.Superlattices and Microstructures,82,599-611.
MLA	Hao, Xuqiang,et al."Behavior of borate complex anion on the stabilities and the hydrogen evolutions of ZnxCo3-xO4 decorated graphene".Superlattices and Microstructures 82(2015):599-611.