A novel Gaussian-DAEM-reaction model for the pyrolysis of cellulose, hemicellulose and lignin | |
Zhang, Jinzhi1,2; Chen, Tianju1; Wua, Jingli1; Wu, Jinhu1 | |
刊名 | RSC ADVANCES |
2014 | |
卷号 | 4期号:34页码:17513-17520 |
英文摘要 | This work deals with the pyrolysis kinetics of cellulose, hemicellulose and lignin. Experiments were carried out in a thermogravimetric analyzer (TGA Q5000) in the inert atmosphere of nitrogen at a heating rate of 10 K min(-1). The single Gaussian distributed activation energy model (DAEM) was utilized to study the pyrolysis kinetics. Kinetic parameters such as the pre-exponential factor (k(o)), mean activation energy (E-o) and standard variance (sigma) were computed by a pattern search algorithm. It was found that the calculated kinetic parameters using the single Gaussian-DAEM-reaction model could reproduce the differential thermogravimetric (DTG) curves of cellulose very well. However, there existed obvious deviations in the whole range of temperatures between the calculated and experimental data for hemicellulose and lignin. In order to describe the thermal decompositions of hemicellulose and lignin more accurately, a novel double Gaussian-DAEM-reaction model consisting of two parallel partial reactions was developed to describe the pyrolysis processes. Calculated results of the fitting procedure using the double GaussianDAEM- reaction model showed good agreement with experimental DTG data of hemicellulose and lignin. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | ACTIVATION-ENERGY MODEL ; THERMAL-DECOMPOSITION ; KINETIC-PARAMETERS ; STRAW PYROLYSIS ; BIOMASS ; GASIFICATION ; CHEMISTRY ; K(0)(E) ; F(E) |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000335227700014 |
内容类型 | 期刊论文 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/6150] |
专题 | 青岛生物能源与过程研究所_热化学转化事业部 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Jinzhi,Chen, Tianju,Wua, Jingli,et al. A novel Gaussian-DAEM-reaction model for the pyrolysis of cellulose, hemicellulose and lignin[J]. RSC ADVANCES,2014,4(34):17513-17520. |
APA | Zhang, Jinzhi,Chen, Tianju,Wua, Jingli,&Wu, Jinhu.(2014).A novel Gaussian-DAEM-reaction model for the pyrolysis of cellulose, hemicellulose and lignin.RSC ADVANCES,4(34),17513-17520. |
MLA | Zhang, Jinzhi,et al."A novel Gaussian-DAEM-reaction model for the pyrolysis of cellulose, hemicellulose and lignin".RSC ADVANCES 4.34(2014):17513-17520. |
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